CAS No.: | 68-12-2 |
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Formula: | C3h7no |
EINECS: | 200-679-5 |
Classification: | Biochemical Reagents |
Specific Usage: | For Biological Purpose |
Content: | Standard |
Samples: |
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N,N-Dimethylformamide Chemical Properties |
Melting point | -61 °C (lit.) |
alpha | 0.94 º |
Boiling point | 153 °C (lit.) |
density | 0.944 g/mL (lit.) |
vapor density | 2.5 (vs air) |
vapor pressure | 2.7 mm Hg ( 20 °C) |
refractive index | n20/D 1.430(lit.) |
Fp | 136 °F |
storage temp. | Store at +5°C to +30°C. |
solubility | water: miscible |
pka | -0.44±0.70(Predicted) |
form | liquid |
color | APHA: ≤15 |
PH | 7 (200g/l, H2O, 20ºC) |
Odor | Faint, ammonia-like odor detectable at 100 ppm |
Relative polarity | 0.386 |
Odor Threshold | 1.8ppm |
explosive limit | 2.2-16%(V) |
Water Solubility | soluble |
λmax | λ: 270 nm Amax: 1.00 λ: 275 nm Amax: 0.30 λ: 295 nm Amax: 0.10 λ: 310 nm Amax: 0.05 λ: 340-400 nm Amax: 0.01 |
Sensitive | Hygroscopic |
Merck | 14,3243 |
BRN | 605365 |
Exposure limits | NIOSH REL: TWA 10 ppm (30 mg/m3), IDLH 500 ppm; OSHA PEL: TWA 10 ppm; ACGIH TLV: TWA 10 ppm (adopted). |
Dielectric constant | 36.710000000000001 |
InChIKey | ZMXDDKWLCZADIW-UHFFFAOYSA-N |
LogP | -1.010 |
CAS DataBase Reference | 68-12-2(CAS DataBase Reference) |
NIST Chemistry Reference | Formamide, N,N-dimethyl-(68-12-2) |
IARC | 2A (Vol. 47, 71, 115) 2018 |
EPA Substance Registry System | N,N-Dimethylformamide (68-12-2) |
Hazard Codes | T |
Risk Statements | 61-20/21-36 |
Safety Statements | 53-45 |
RIDADR | UN 2265 3/PG 3 |
WGK Germany | 1 |
RTECS | LQ2100000 |
F | 3-10 |
Autoignition Temperature | 445 °C |
Hazard Note | Toxic |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | III |
HS Code | 29241990 |
Hazardous Substances Data | 68-12-2(Hazardous Substances Data) |
Toxicity | LD50 in mice, rats (ml/kg): 6.8, 7.6 orally; 6.2, 4.7 i.p. (Bartsch) |
IDLA | 500 ppm |
N,N-Dimethylformamide (DMF) is a clear liquid that has been widely used in industries as a solvent, an additive, or an intermediate because of its extensive miscibility with water and most common organic solvents. Dimethylformamide solutions are used toprocess polymer fibers, films, and surface coatings; to permit easy spinning of acrylic fibers; to produce wire enamels, and as a crystallization medium in the pharmaceutical industry.
DMF can also be used for formylation with alkyllithium or Grignard reagents. It is used as a reagent in Bouveault aldehyde synthesis and also in Vilsmeier-Haack reaction. It acts as a catalyst in the synthesis of acyl chlorides. It is used for separating and refining crude from olefin gas. DMF along with methylene chloride acts as a remover of varnish or lacquers. It is also used in the manufacture of adhesives, fibers and films.1. Can I get samples?
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